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Abstract Alkaline iron (Fe) batteries are attractive due to the high abundance, low cost, and multiple valent states of Fe but show limited columbic efficiency and storage capacity when forming electrochemically inert Fe₃O₄on discharging and parasitic H₂on charging. Herein, sodium silicate is found to promote Fe(OH)₂/FeOOH against Fe(OH)₂/Fe₃O₄conversions. Electrochemical experiments,operandoX‐ray characterization, and atomistic simulations reveal that improved Fe(OH)₂/FeOOH conversion originates from (i) strong interaction between sodium silicate and iron oxide and (ii) silicate‐induced strengthening of hydrogen‐bond networks in electrolytes that inhibits water transport. Furthermore, the silicate additive suppresses hydrogen evolution by impairing energetics of water dissociation and hydroxyl de‐sorption on iron surfaces. This new silicate‐assisted redox chemistry mitigates H₂and Fe₃O₄formation, improving storage capacity (199 mAh g⁻¹in half‐cells) and coulombic efficiency (94 % after 400 full‐cell cycles), paving a path to realizing green battery systems built from earth‐abundant materials.